Franklin International
MATERIAL SAFETY DATA SHEET

MSDS Name: Titebond Solvent Free Fast Grab FRP Adhesive
MSDS Number: 4054
Revision Date: 3/26/08
 
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION                         
Product Name:                Titebond Solvent Free Fast Grab FRP                
                             Adhesive                                           
CAS Number:                  none                                               
HMIS Hazard Rating:          Health: 1  Fire: 1  Reactivity: 0                  
 
Company Identification:      Franklin International
                             2020 Bruck Street
                             Columbus OH 43207
 
 
Contact:                     Franklin Technical Services                        
Telephone/Fax:               (800) 877-4583 (614) 445-1493                      
Emergency Phone (24 Hour):   Franklin Security                                  
                             (614) 445-1300                                     
Chemtrec (24 Hour):          (800) 424-9300                                     
Chemtrec International:      (703) 527-3887                                     
 
Product Class                Solvent Free adhesive                              
Product Use:                 FRP adhesive                                       
Product Code:                3432                                               
 
Division:                    Construction Adhesives & Sealants                  
 
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS                          
Hazardous Ingredients                     CAS Number       Percent              
Product contains no hazardous ingredients or they are below reportable levels.  
 
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.                
 
SECTION 3 - HAZARD IDENTIFICATION                                               
 
EMERGENCY OVERVIEW:                                                             
Light brown colored mastic. Slippery in the wet state. Do not ingest.           
Avoid prolonged exposure to skin or vapors. KEEP OUT OF REACH OF                
CHILDREN.                                                                       
ROUTES OF ENTRY:                                                                
Ingestion:     Yes                                                              
Inhalation:    Yes                                                              
Skin:          Yes                                                              
Eye:           Yes                                                              
INHALATION:                                                                     
May be irritating to upper respiratory tract.                                   
INGESTION:                                                                      
Ingestion is not a probable route of exposure. Harmful if swallowed.            
SKIN:                                                                           
Prolonged or repeated skin contact can cause irritation.                        
EYE:                                                                            
Mildly irritating to eyes.                                                      
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:                                      
Under conditions of normal use chronic affects are not expected.                
Possible aggravation of pre-exsisting skin conditions.                          
CARCINOGENICITY:                                                                
IARC: No                                                                        
 
NTP:  No                                                                        
OSHA: No                                                                        
REPRODUCTIVE TOXICITY:                                                          
This product has not been evaluated for reproductive toxicity.                  
TARGET ORGANS:                                                                  
Eyes and skin.                                                                  
 
SECTION 4 - FIRST AID MEASURES                                                  
 
INHALATION:                                                                     
Remove to fresh air. If difficulty persists, seek medical attention.            
INGESTION:                                                                      
Call poison control center immediately.  Follow their specific                  
instructions.  Do not induce vomiting.                                          
SKIN:                                                                           
Wash with soap and water.  Contact a physician if irritation develops           
or persists.                                                                    
EYE:                                                                            
Hold eyelids apart and flush with plenty of water for at least 15               
minutes. Seek medical attention.                                                
 
SECTION 5 - FIRE-FIGHTING MEASURES                                              
Flammability Class (OSHA)    IIIB                                               
Flash Point:                 > 200.øF                                           
                             Setaflash                                          
Explosive Range:             Not applicable                                     
 
 
EXTINGUISHING MEDIA:                                                            
Use alcohol foam, carbon dioxide, water spray, or ABC dry chemical              
when fighting fires involving this product.                                     
HAZARDOUS COMBUSTION PRODUCTS:                                                  
Oxides of carbon may be released during combustion.                             
FIRE FIGHTING PROCEDURES:                                                       
Wear a NIOSH approved self-contained breathing apparatus.                       
 
SECTION 6 - ACCIDENTAL RELEASE MEASURES                                         
 
CONTAINMENT TECHNIQUES:                                                         
Use inert absorbent to dike the spill. Keep away from drains.                   
CLEAN-UP:                                                                       
Spread absorbent over material and scrape up material/absorbent and             
place in an approved container. If product has dried scrape up and              
place in an approved container.                                                 
EMERGENCY MEASURES:                                                             
Isolate hazard area.  Keep unnecessary and unprotected personnel from           
entering area.  Wear all appropriate personal protection equipment              
(PPE) (see Section 8).                                                          
 
SECTION 7 - HANDLING AND STORAGE                                                
 
HANDLING:                                                                       
Wash thoroughly after handling.                                                 
Avoid prolonged or repeated contact with the skin.                              
STORAGE:                                                                        
Keep from freezing.                                                             
PRECAUTIONARY STATEMENT:                                                        
Keep out of the reach of children.                                              
 
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION                           
Occupational Exposure Limits                                                    
           ACGIH TLV     ACGIH TLV-C   ACGIH STEL    OSHA STEL     OSHA PEL     
 
ENGINEERING CONTROLS:                                                           
Use local exhaust as needed to maintain occupational exposure limits.           
OTHER:                                                                          
Facilities storing or utilizing any chemical should be equipped with            
an eyewash facility and a safety shower.                                        
RESPIRATORY PROTECTION:                                                         
Respiratory protection is not expected to be necessary under normal             
use. Follow requirements for respiratory protection in OSHA 1910.134.           
EYE PROTECTION:                                                                 
Chemical splash goggles (ANSI Z87.1 or approved equivalent).                    
SKIN PROTECTION:                                                                
Where skin contact can occur, wear impervious gloves.                           
 
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES                                    
Form:                        Mastic                                             
Appearance/Color:            Light brown                                        
Odor:                        Mild                                               
Solubility (in water):       Miscible                                           
pH Value:                    5.                                                 
Boiling Range/Point:         212.øF                                             
Evaporation Rate:            Slower than n-Butyl Acetate                        
 
% Volatile:                  33.%                                               
Specific Gravity:            1.39                                               
VOC:                         2.6 g/l                                            
 
 
SECTION 10 - STABILITY AND REACTIVITY                                           
Stability:                   This product is stable                             
Hazardous Polymerization:    Hazardous polymerization will not occur            
 
CONDITIONS TO AVOID:                                                            
Strong acids and strong bases                                                   
INCOMPATIBLITY:                                                                 
Easily oxidizable materials.                                                    
 
SECTION 11 - TOXICOLOGICAL INFORMATION                                          
 
This formulation has a low order of acute and chronic toxicity by all           
routes of exposure.  Prolonged or repeated exposure may cause skin              
irritation.  Direct contact may cause eye irritation.                           
 
Exposure to any chemical substance, including those with a low order            
of toxicity, should be controlled and minimized to avoid harmful                
effects.                                                                        
 
 
SECTION 12 - ECOLOGICAL INFORMATION                                             
 
This formulation has not been tested for environmental effects.                 
 
SECTION 13 - DISPOSAL CONSIDERATIONS                                            
 
WASTE DISPOSAL:                                                                 
Disposal of this product must comply with all applicable federal,               
state and local regulations.                                                    
CONTAINER DISPOSAL:                                                             
Disposal of this container should comply with all applicable federal,           
state and local regulations.                                                    
 
SECTION 14 - TRANSPORT INFORMATION                                              
UN Number                    none                                               
UN Pack Group                N/A                                                
UN Class                     Nonhaz                                             
ICAO/IATA Class              Nonhazardous                                       
IMDG Class                   Nonhazardous                                       
Shipping Name                Nonhazardous                                       
 
 
Packaging may not be approved for shipping by air. Please contact               
Franklin International for further information.                                 
 
SECTION 15 - REGULATORY INFORMATION                                             
 
TSCA (Toxic Substances Control Act Inventory):                                  
All components of this product are listed on the TSCA inventory except          
as exempted.                                                                    
PENNSYLVANIA:                                                                   
Hazardous components required to be listed at 1% or more:                       
calcium carbonate; limestone; 1317-65-3                                         
kaolin clay; kaolin; 1332-58-7                                                  
Non-hazardous components required to be listed at 3% or more:                   
urea 57-13-6; dipropylene glycol dibenzoate 27138-31-4; polyvinyl               
acetate emulsion 24980-61-8; water 7732-18-5                                    
NEW JERSEY:                                                                     
polyvinyl acetate emulsion 24980-61-8; water 7732-18-5; clay                    
1332-58-7; calcium carbonate 1317-65-3; dipropylene glycol dibenzoate           
27138-31-4                                                                      
 
SECTION 16 - OTHER INFORMATION                                                  
 
DISCLAIMER:                                                                     
While the information and recommendations set forth herein are                  
believed to be accurate as of the data hereof, Franklin International           
makes no warranty, express or implied, with respect thereto and                 
disclaims all liability from reliance thereon.